Different Anode Catalyst Analysis Performance Comparison by Low Temperature Direct Chloro Ethanol Fuel Cell
DOI:
https://doi.org/10.53555/ans.v2i3.111Keywords:
Direct methanol fuel cell;, Direct ethanol fuel cell, PtRu anode;, PtSn anodeAbstract
The single fuel cell using PtSn/C as anode catalyst at 90 ◦C shows similar power densities whenever fueled by methanol or ethanol. The cyclic voltammetry (CV) and single fuel cell tests indicated that PtRu is more suitable for DMFC while PtSn is more suitable for DEFC. It was found that the addition of Ru or Sn to the Pt dramatically enhances the electro-oxidation of both methanol and ethanol. It was also found that the single cell adopting PtRu/C as anode shows better DMFC performance, while PtSn/C catalyst shows better DEFC performance. Lowtemperature polymer electrolyte membrane fuel cells directly fed by methanol and ethanol were investigated employing carbon supported Pt, PtSn and PtRu as anode catalysts, respectively. Employing Pt/C as anode catalyst, both direct methanol fuel cell (DMFC) and direct ethanol fuel cell (DEFC) showed poor performances even in presence of high Pt loading on anode.
Downloads
References
S.C. Thomas, X.M. Ren, S. Gottsfeld, P. Zelenay, Electrochim. Acta47 (2002) 3741–3748.
H. Dohle, H. Schmitz, T. Bewer, J. Mergel, D. Stolten, J. PowerSources 106 (1–2) (2002) 313–322.
T. Schultz, S. Zhou, K. Sundmacher, Chem. Eng. Technol. 24 (12)(2001) 1223–1233.
V. Antonucci, Fuel Cells Bull. 7 (2002) 6–8.
A.S. Aricò, S. Srinicasan, V. Antonucci, Fuel Cells 1 (2) (2001)1–29.
S. Wasmus, A. Kuver,J. Electroanal. Chem. 461 (1–2) (1999) 14–31.
M. Baldauf, D.M. Kolb, J. Phys. Chem. 100 (1996) 11375–11381.
N.M. Markovic, H.A. Gasteiger, P.N. Ross Jr., Electrochim. Acta40 (1) (1995) 91–98.
S. Park, Y. Xie, M.J. Weaver, Langmuir 18 (2002) 5792–5798.
C. Rice, S. Ha, R.I. Masel, P. Waszczuk, A. Wieckowski, T. Barnard,J. Power Sources 111 (2002) 83–89.
T. Zerihun, P. Grundler, J. Electroanal. Chem. 441 (1998) 57–63.
C. Lamy, E.M. Belgsir, J.M. Leger, J. Appl. Electrochem. 31 (2001)799–809.
E. Peled, V. Livshits, T. Duvdevani, J. Power Sources 106 (2002)245–248.
A.S. Aricò, P. Creti, P.L. Antonucci, V. Antonucci, Electrochem.Solid State Lett. 1 (2) (1998) 66–68.
K.T. Adjemain, S. Srinivasan, J. Benziger, A.B. Bocarsly, J. PowerSources 109 (2002) 356–364.
K.W. Park, J.H. Choi, B.K. Kwon, S.A. Lee, Y.E. Sung, H.Y. Ha,S.A. Hong, H. Kim, A. Wieckowski, J. Phy. Chem. B 106 (2002)1869–1877.
B. Gurau, R. Viswanathan, R.X. Liu, T.J. Lafrenz, K.L. Ley, E.S.Smotkin, E. Reddington, A. Sapienza, B.C. Chan, T.E. Mallouk, S.Sarangapani, J. Phys. Chem. B 102 (49) (1998) 9997–10003.
F. Delime, J.M. Léger, C. Lamy, J. Appl. Electrochem. 29 (1999)1249–1254.
C. Lamy, A. Lima, V. LeRhun, F. Delime, C. Coutanceau, J.M.Léger, J. Power Sources 105 (2002) 283–296.
W. Zhou, Z. Zhou, S. Song, W. Li, G. Sun, et al., Appl. Catal. B,in press.
Z. Zhou, S. Wang, W. Zhou, G. Wang, L. Jiang, et al., Chem.Commun. 3 (2003) 394–395.
Z.B. Wei, S.L. Wang, B.L.Yi, J.G. Liu, L.K. Chen, W.J. Zhou, W.Z.Li, Q. Xin, J. Power Sources 106 (2002) 364–369.
Z.B. Wei, J.G. Liu, Y.G. Qiao, W.J. Zhou, W.Z. Li, L.K. Chen, B.L.Yi, Q. Xin, Chin. Electrochem. 7 (2001) 228–233.
W.J. Zhou, W.Z. Li, Z.H. Zhou, S.Q. Song, Z.B. Wei, P. Tsiakaras,Q. Xin, Chem. J. Chin. Univ. 5 (2003) 858–862.
A. Hamnett, Catal. Today 38 (4) (1997) 445–457.
H.A. Gasteiger, N. Markoviæ, P.N. Ross Jr., E.J. Cairns, J. Electrochem.Soc. 141 (7) (1994) 1795–1803.
E. Antolini, Mater. Chem. Phys. 78 (2003) 563–573.
A.S. Aricò, A.K. Shukla, K.M. El-Khatib, P. Cret`ı, V. Antonucci, J.Appl. Electrochem. 29 (6) (1999) 671–676.
A. Hamnett, B.J. Kennedy, Electrochim. Acta 33 (11) (1988) 1613–1618.
S.A. Campbell, R. Parsons, J. Chem. Soc., Faraday Trans. 88 (6)(1992) 833–841.
A. Aramata, I. Toyashima, M. Enyo, Electrochim. Acta 37 (8) (1992)1317–1320.
Y. Morimoto, E.B. Yeager, J. Electroanal. Chem. 444 (1) (1998)95–100.
M. Götz, H. Wendt, Electrochim. Acta 43 (24) (1998) 3637–3644.
A.N. Haner, P.N. Ross, J. Phys. Chem. 95 (9) (1991) 3740–3746.
H.A. Gasteiger, N. Markovic, P.N. Ross Jr., J. Phys. Chem. 99 (22)(1995) 8945–8949.
R. Parson, T. Vandernoo, J. Electroanal. Chem. 257 (1988) 9–45.
J.M. Pérez, B. Beden, F. Hahn, A. Aldaz, C. Lamy, J. Electroanal.Chem. 262 (1989) 251–261.
N. Furuya, M. Shibata, J. Electroanal. Chem. 266 (1989) 461–464.
S.C. Chang, L.W. Leung, M.J. Weaver, J. Phys. Chem. 94 (1990)6013–6021.
C.T.Hable, M.S. Wrighton, Langmuir 7 (1991) 1305–1309.
T. Iwasita, E. Pastor, Electrochim. Acta 39 (1994) 531–537.
W.T. Napporn, J.M. Léger, C. Lamy, J. Electroanal. Chem. 408(1996) 141–147.
W.T. Napporn, J.M. Léger, C. Lamy, J. Electroanal. Chem. 404(1996) 153–159.
M.A.A. Rahim, M.W. Khalil, H.B. Hassan, J. Appl. Electrochem.30 (10) (2000) 1151–1155.
M. Watanabe, S. Motoo, J. Electroanal. Chem. 60 (1975) 275–283.[46] S. Mukerjee, J. McBreen, J. Electrochem. Soc. 146 (2) (1999) 600–606.[47] K.Wang, H.A. Gasteiger, N.M. Markovic, P.N. Ross Jr., Electrochim.Acta 41 (16) (1996) 2587–2593
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2016 gnpublication@
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
In consideration of the journal, Green Publication taking action in reviewing and editing our manuscript, the authors undersigned hereby transfer, assign, or otherwise convey all copyright ownership to the Editorial Office of the Green Publication in the event that such work is published in the journal. Such conveyance covers any product that may derive from the published journal, whether print or electronic. Green Publication shall have the right to register copyright to the Article in its name as claimant, whether separately
or as part of the journal issue or other medium in which the Article is included.
By signing this Agreement, the author(s), and in the case of a Work Made For Hire, the employer, jointly and severally represent and warrant that the Article is original with the author(s) and does not infringe any copyright or violate any other right of any third parties, and that the Article has not been published elsewhere, and is not being considered for publication elsewhere in any form, except as provided herein. Each author’s signature should appear below. The signing author(s) (and, in